115397-11-0Relevant academic research and scientific papers
Nonhydride mechanism of metal-catalyzed hydrosilylation
Shirobokov, Oleg G.,Kuzmina, Lyudmila G.,Nikonov, Georgii I.
, p. 6487 - 6489 (2011)
A 1:1:1 reaction between complex (Tp)(ArN=)Mo(H)(PMe3) (3), silane PhSiD3, and carbonyl substrate established that hydrosilylation catalyzed by 3 is not accompanied by deuterium incorporation into the hydride position of the catalyst, thus ruling out the conventional hydride mechanism based on carbonyl insertion into the M-H bond. An analogous result was observed for the catalysis by (O=)(PhMe2SiO)Re(PPh 3)2(I)(H) and (Ph3PCuH)6.
A Masked Cuprous Hydride as a Catalyst for Carbonyl Hydrosilylation in Aqueous Solutions
Ritter, Florian,Mukherjee, Debabrata,Spaniol, Thomas P.,Hoffmann, Alexander,Okuda, Jun
, p. 1818 - 1822 (2019)
Redox-unstable cuprous hydridotriphenylborate was isolated as an N-heterocyclic carbene adduct [(IPr)Cu(HBPh3)] (IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with good thermal stability. Although this compound displays a contact ion-pa
Highly efficient large bite angle diphosphine substituted molybdenum catalyst for hydrosilylation
Chakraborty, Subrata,Blacque, Olivier,Fox, Thomas,Berke, Heinz
, p. 2208 - 2217 (2013/10/22)
Treatment of the complex Mo(NO)Cl3(NCMe)2 with the large bite angle diphosphine, 2,2′-bis(diphenylphosphino)diphenylether (DPEphos) afforded the dinuclear species [Mo(NO)(PaP)Cl 2]2[μCl]2 (PaP = DPEph
