1154063-29-2Relevant academic research and scientific papers
Nucleophilic carbene-mediated hydrophosphonylation of aldimines
Cai, Zhi-Hua,Du, Guang-Fen,Dai, Bin,He, Lin
supporting information; experimental part, p. 694 - 698 (2012/04/10)
Aldimines undergo efficient hydrophosphonylation reactions with dimethyl phosphite in the presence of nucleophilic heterocyclic- carbenes (NHCs) as organocatalysts to give the corresponding (α-aminoalkyl)phosphonates in moderate-to-excellent yields. Georg
Hydrophosphonylation of aldimines under catalysts-free conditions
Cai, Zhihua,Fan, Yecheng,Du, Guangfen,He, Lin
experimental part, p. 1658 - 1662 (2012/09/07)
Trimethylsilyl phosphite reacted with aldimines efficiently under catalysts-free conditions, giving α-aminophosphonates in good to excellent yields. Furthermore, the reaction can be scaled-up easily and the high yield can be maintained. Copyright
Iodine-catalyzed efficient hydrophosphonylation of N-tosyl aldimines
Das, Biswanath,Balasubramanyam, Penagaluri,Krishnaiah, Maddeboina,Veeranjaneyulu, Boyapati,Reddy, Gandolla Chinna
supporting information; experimental part, p. 4393 - 4395 (2009/09/06)
(Chemical Equation Presented) Treatment of N-tosyl aldimines with dialkyl trimethylsilyl phosphites at 0°C in the presence of iodine as a catalyst afforded the corresponding sulfonamide phosphonates in excellent yields within 1.5 to 2.5 h.
