115407-73-3Relevant academic research and scientific papers
Masked Lithium Bishomoenolates: Useful Intermediates in Organic Synthesis
Ramon, Diego J.,Yus, Miguel
, p. 3825 - 3831 (2007/10/02)
The lithiation of the chloro ketals 9 with lithium naphthalenide at -78 deg C led to the corresponding masked lithium bishomoenolates 4, which are stable species under these conditions and react with different electrophilic reagents (H2O, D2O, i-PrCOH, Ph
Lactones, XX. - Grignardation Followed by Phase-Transfer Oxidation: A Convenient Synthesis of δ,δ-Disubstituted δ-Lactones from δ-Valerolactone
Lehmann, Jochen,Marquardt, Norbert
, p. 827 - 832 (2007/10/02)
A Grignardation-oxidation sequence, without isolation of intermediates, easily transfers δ-valerolactone (4) into Δ,δ-disubstituted δ-lactones 6.The synthesis of δ,δ-diphenyl-δ-valerolactone (6a) served as an exsample for a detailed investigation of the r
