115408-35-0Relevant academic research and scientific papers
Conformational Effects in 2-Deoxyglucopyranos-1-yl Radicals
Korth, Hans-Gert,Sustmann, Reiner,Giese, Bernd,Rueckert, Brigitte,Groeninger, Kai Stefan
, p. 1891 - 1898 (2007/10/02)
2-Unsubstituted and 2-substituted (fluoro, tosylamino, n-propyl) 3,4,6-tri-O-acetyl-2-deoxypyranosyl radicals are obtained by reaction of the corresponding pyranosyl bromides or phenylselenides with photolytically generated trimethyltin radicals in benzen
Dimerization of Carbohydrate Radicals
Giese, Bernd,Rueckert, Brigitte,Groeninger, Kay Stefan,Muhn, Ralf,Lindner, Hans Joerg
, p. 997 - 1000 (2007/10/02)
Glycosyl bromides and selenides 1 react with hexamethylditin to give coupling products 2-4 in 32percent yield.The reactions occur by dimerization of glycosyl radicals, the radical 8 in the 4C1 chair conformation being slightly more s
