115414-21-6

Basic information

• Product Name: 5-deoxy-5-C-<(ethoxy)phenylphosphinothioyl>-1,2-O-isopropylidene-3-O-methyl-α-D-xylofuranose
• CAS NO: 115414-21-6
• Molecular Weight: 372.422
• Mol File: 115414-21-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-deoxy-5-C-<(ethoxy)phenylphosphinothioyl>-1,2-O-isopropylidene-3-O-methyl-α-D-xylofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 5-deoxy-5-C-<(ethoxy)phenylphosphinothioyl>-1,2-O-isopropylidene-3-O-methyl-α-D-xylofuranose(115414-21-6)
• EPA Substance Registry System: 5-deoxy-5-C-<(ethoxy)phenylphosphinothioyl>-1,2-O-isopropylidene-3-O-methyl-α-D-xylofuranose(115414-21-6)

Safety Data

• Hazardous Substances Data: 115414-21-6(Hazardous Substances Data)

Upstream product

• 6591-08-8 phenyl-thiophosphonigsaeure-O-ethylester 
• 85426-94-4 5-deoxy-5-iodo-1,2-O-isopropylidene-3-O-methyl-α-D-xylofuranose 

Downstream Products

• 115414-26-1 1,2,4-tri-O-acetyl-5-deoxy-3-O-methyl-5-C-<(S)-phenylphosphinothioyl>-β-D-xylopyranose 
• 115414-26-1 1,2,4-tri-O-acetyl-5-deoxy-3-O-methyl-5-C-<(S)-phenylphosphinothioyl>-α-D-xylopyranose 
• 115414-23-8 5-deoxy-1,2-O-isopropylidene-3-O-methyl-5-C-phenylphosphinothioyl-α-D-xylofuranose 

Relevant articles and documents

Synthesis and Characterization of Deoxy-3-O-methyl-5-C--α- and β-D-xylopyranoses. The First Sugar Analogue Having a Phosphinothioyl Group in the Hemiacetal Ring

Treatment of 5-deoxy-5-iodo-1,2-O-isopropylidene-3-O-methyl-α-D-xylofuranose with ethyl phenylphosphinothioate in the presence of sodium hydride, followed by the reduction with sodium dihydrobis-(2-methoxyethoxy)aluminate, and then with 0.5 M HCl-EtOH gav