115463-94-0Relevant academic research and scientific papers
On the early steps of cineol biosynthesis in Eucalyptus globulus
Rieder, Christoph,Jaun, Bernhard,Arigoni, Duilio
, p. 2504 - 2513 (2000)
Samples of [4-2H1]-1-deoxyxylutose (17a) and [2-13C, 4-2H1]-1-deoxyxylulose (17b), have been prepared by modification of known procedures and fed in aqueous solution to twiglets of Eucalyptus globulus
C-H Bond Cleavage Is Rate-Limiting for Oxidative C-P Bond Cleavage by the Mixed Valence Diiron-Dependent Oxygenase PhnZ
Gama, Simanga R.,Lo, Becky Suet Yan,Séguin, Jacqueline,Pallitsch, Katharina,Hammerschmidt, Friedrich,Zechel, David L.
, p. 5271 - 5280 (2019)
PhnZ utilizes a mixed valence diiron(II/III) cofactor and O2 to oxidatively cleave the carbon-phosphorus bond of (R)-2-amino-1-hydroxyethylphosphonic acid to form glycine and orthophosphate. The active site residues Y24 and E27 are proposed to
Biosynthesis of Natural Products with a P-C Bond, III. - Synthesis of (R)- and (S)-(2-Aminoethyl)phosphonic Acid and Hydroxylation to (2-Amino-1-hydroxyethyl)phosphonic Acid in Acanthamoeba castellanii (Neff)
Hammerschmidt, Friedrich
, p. 955 - 960 (2007/10/02)
(Benzyloxy)acetaldehyde (4) was reduced to give (S)-(+)-2-(benzyloxy)ethanol (5) by horse liver alcohol dehydrogenase/NAD+/EtOH.This chiral alcohol was transformed into (R)- and (S)-(2-aminoethyl)phosphonic acid (AEP) (13).The enantiomer
