115465-59-3

Upstream product

• 115438-65-8 3,5-O-benzylidene-6,7-dideoxy-1,2-O-isopropylidene-α-D-gluco-octose 
• 115438-63-6 (E)-3-((3aR,3bS,7R,7aR,8aR)-2,2-Dimethyl-5-phenyl-tetrahydro-[1,3]dioxolo[4,5]furo[3,2-d][1,3]dioxin-7-yl)-acrylic acid ethyl ester 
• 115438-64-7 ethyl 3,5-O-benzylidene-6,7-dideoxy-1,2-O-isopropylidene-α-D-gluco-octuronate 
• 115438-66-9 3,5-O-benzylidene-6,7-dideoxy-1,2-O-isopropylidene-8-O-mesyl-α-D-gluco-octose 
• 22164-09-6 3,5-O-benzylidene-1,2-O-isopropylidene-α-<*>-glucofuranose 

Downstream Products

• 115438-57-8 5,8-benzyloxycarbonylimino-5,6,7,8-tetradeoxy-D-gluco-octose 
• 115438-59-0 5,6,7,8-tetradeoxy-5,8-(N-benzyloxycarbonylimino)-1,2-O-isopropylidene-α-D-gluco-oct-1,4-furanose 
• 115649-93-9 1-deoxy-castanospermine 
• 120191-68-6 (R)-2-((2R,3S,4R,5R)-3,4,5-Triacetoxy-tetrahydro-furan-2-yl)-pyrrolidine-1-carboxylic acid benzyl ester 

Relevant academic research and scientific papers

ENANTIOSPECIFIC SYNTHESIS OF POLYHYDROXYLATED INDOLIZIDINES RELATED TO CASTANOSPERMINE: 1-DEOXY-CASTANOSPERMINE

Enantiospecific synthesis of (6S,7R,8R,8aR)-6,7,8-trihydroxyindolizidine (1-deoxy-castanospermine) (3) is described from readily available D-glucose, where the key step involves oxidative bromination of a benzylidene acetal to afford 8-azido-3-O-benzoyl-5