115479-62-4

Upstream product

• 115479-57-7 dimethyl 3-exo-acetoxy-5,6-endo-bis(benzyloxy)-7-oxabicyclo<2.2.1>heptane-2,2-dicarboxylate 
• 53996-40-0 3,4-bis(benzoloxy)furan 
• 115479-55-5 dimethyl 6-exo-acetoxy-2,3-bis(benzyloxy)-7-oxabicyclo<2.2.1>hept-2-ene-5,5-dicarboxylate 

Downstream Products

• 115479-64-6 3-Acetoxy-2-((2S,3S,4R,5S)-5-acetoxy-3,4-bis-benzyloxy-tetrahydro-pyran-2-yl)-propionic acid methyl ester 

Relevant academic research and scientific papers

Diels-Alder Reaction of Dimethyl Acetoxymethylenemalonate with 3,4-Dialkoxyfurans and the Utility of Its Adducts in the Stereospecific Synthesis of Lyxopyranosyl C-Glycosides

Dimethyl lyxopyranosylmalonates were synthesized in stereospecific manner from the adducts obtained from Diels-Alder reaction of 3,4-dialkoxyfurans and dimethyl acetoxymethylenemalonate, through retrograde aldol C-C bond fission under reductive condition as a key step.