115508-75-3

Upstream product

• 73814-75-2 [(2S,3S)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxiranyl]-methanol 
• 157945-01-2 (S)-tert-butyl (3S,4R)-5-(benzyloxy)-3-hydroxy-4-methylpentanethioate 

Downstream Products

• 1061264-36-5 {[(2R,3S)-3,5-bis(tert-butyldimethylsiloxy)-2-methylpentyloxy]methyl}benzene 

Relevant academic research and scientific papers

A practical synthesis of the C1-C9 fragment of dictyostatin

A stereoselective synthesis of the C1-C9 fragment of (-)-dictyostatin has been achieved by use of a titanium(IV) chloride mediated chelation-controlled Mukaiyama aldol reaction and two modified Horner-Wadsworth-Emmons olefinations (Roush-Masamune and Stil

REDUCTIVE RING OPENINGS OF ALLYL-ALCOHOL EPOXIDES

Red-Al reduction of allyl-alcohol epoxides was shown to yield 1,3-diols in high regioselectivity, while DIBAL reduction was shown to yield 1,2-diols.