115534-75-3Relevant academic research and scientific papers
Electronic absorption spectra of diorganogermylenes in matrices: Formation of diorganogermylene complexes with heteroatom-containing substrates
Ando, Wataru,Itoh, Hiroyuki,Tsumuraya, Takeshi
, p. 2759 - 2766 (2008/10/08)
Diorganogermylenes were generated in hydrocarbon matrices at 77 K by the photolysis of 7-germanorbornadienes 1a-e or bis(trimethylsilyl)germanes 2a-g. The germylenes show electronic absorption bands at 420-558 nm. The germylenes react with heteroatom-containing substrates (R2O, R2S, R3P, R3N, RCl, and ROH) to form adducts, which show characteristic absorption bands at shorter wavelengths than those of germylenes.
Spectroscopic characterization of diarylgermylene complexes with heteroatom-containing substrates
Ando, Wataru,Itoh, Hiroyuki,Tsumuraya, Takeshi,Yoshida, Hitoaki
, p. 1880 - 1882 (2008/10/08)
Characteristic UV absorption bands of diarylgermylene complexes were observed in the reaction of diarylgermylenes with heteroatom-containing substrates in 3-MP/IP matrix at 77 K.
