115560-91-3

Upstream product

• 115560-89-9 (2R)-(Z)-1-(phenylmethoxy)-4-hexen-2-ol 
• 115560-90-2 (2R)-(E)-1-(phenylmethoxy)-4-hexen-2-ol 
• 14618-80-5 (R)-benzyl glycidol 

Downstream Products

• 115649-53-1 (2R,4S,5R,6R,7S)-6,7-epoxy-2-<(1,1-dimethylethyl)dimethylsiloxy>-5,7-dimethyl-1-(phenylmethoxy)-8-nonene-4,6-diol 
• 115560-95-7 (2R,4S,5R,6R,7R)-6,7-epoxy-2-<(1,1-dimethylethyl)dimethylsiloxy>-5,7-dimethyl-1-(phenylmethoxy)-8-nonene-4,6-diol 
• 115649-51-9 (2R,4S,5R,6S,7R)-6,7-epoxy-2-<(1,1-dimethylethyl)dimethylsiloxy>-5-methyl-1-(phenylmethoxy)-6-octan-4-ol 
• 115560-94-6 (2R,4S,5S,6S,7R)-6,7-epoxy-2-<(1,1-dimethylethyl)dimethylsiloxy>-5-methyl-1-(phenylmethoxy)-6-octan-4-ol 
• 115649-47-3 (2R,4S,5R)-(6E)-2-<(1,1-dimethylethyl)dimethylsiloxy>-5-methyl-1-(phenylmethoxy)-6-octen-4-ol 
• 115560-93-5 (2R,4S,5R)-(6Z)-2-<(1,1-dimethylethyl)dimethylsiloxy>-5-methyl-1-(phenylmethoxy)-6-octen-4-ol 
• 115560-92-4 (2R,4S,5R)-4,5-epoxy-1-(phenylmethoxy)hexan-2-ol (1,1-dimethylethyl)dimethylsilyl ether 

Relevant academic research and scientific papers

Acyclic Control of Stereochemistry via a Reiterative (E or Z)-1-Propenyllithium-Derived Cuprate Opening of a Chiral Epoxide/Reepoxidation Sequence

The 1,3-relationship between syn hydroxyl and syn or anti methyl groups can be established in a homochiral fashion by using a regioselective (Z)- or (E)-propenyllithium-based cuprate opening of a chiral epoxide, followed by stereoselective reepoxidation.T