115649-72-4Relevant academic research and scientific papers
Highly stereoselective synthesis of C-vinyl pyranosides via a Pd 0-mediated cycloetherification of 1-acetoxy-2,3-dideoxy-oct-2-enitols
Nolen, Ernest G.,Ezeh, Vivian C.,Feeney, Matthew J.
, p. 43 - 47 (2014/08/18)
Oct-2-enitols undergo a Pd0-mediated cyclization to produce C-vinyl α-gluco- and α-galactopyranosides, and C-vinyl β-mannopyranoside in good yield and with high stereoselectivity. While substrate control demonstrates a clear stereochemical pref
Vinylation-Electrophilic Cyclization of Aldopentoses: Easy and Stereoselective Access to C-Glycopyranosides of Rare Sugars
Boschetti, Anna,Nicotra, Francesco,Panza, Luigi,Rosso, Giovanni
, p. 4181 - 4185 (2007/10/02)
A new C-glycosylation procedure, which involves vinylation of a properly protected aldopentose and mercuriocyclization of the obtained glycoenitol, is described; it allows C-glycopyranosides of rare sugars to be obtained from easily available pentoses. 2,
