115655-93-1

Basic information

• Product Name: (6R)-6-[(2R)-2-hydroxy-6-methylhept-5-en-2-yl]cyclohex-2-en-1-one
• CAS NO: 115655-93-1
• Molecular Formula: C₁₄H₂₂O₂
• Molecular Weight: 222.3233
• Mol File: 115655-93-1.mol

Chemical Properties

• Boiling Point: 357.9°C at 760 mmHg
• Flash Point: 152.6°C
• Density: 1.013g/cm³
• Vapor Pressure: 1.46E-06mmHg at 25°C
• Refractive Index: 1.509
• CAS DataBase Reference: (6R)-6-[(2R)-2-hydroxy-6-methylhept-5-en-2-yl]cyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (6R)-6-[(2R)-2-hydroxy-6-methylhept-5-en-2-yl]cyclohex-2-en-1-one(115655-93-1)
• EPA Substance Registry System: (6R)-6-[(2R)-2-hydroxy-6-methylhept-5-en-2-yl]cyclohex-2-en-1-one(115655-93-1)

Safety Data

• Hazardous Substances Data: 115655-93-1(Hazardous Substances Data)

Upstream product

• 129436-61-9 Diethyl-carbamic acid (1R,6S)-6-((R)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-cyclohex-2-enyl ester 
• 129436-54-0 Diethyl-carbamic acid (1S,6R)-6-acetyl-3-methyl-cyclohex-2-enyl ester 
• 37586-57-5 4-methyl-3-pentenylmagnesium bromide 

Relevant articles and documents

O-1-(1,3-butadienyl) carbamates as diels-alder dienes: Stereospecific synthesis of (±)-Hernandulcin and congeners

The TiCl4-catalyzed addition of the title reactants to vinyl ketones regio- and stereospecifically yields cis-disubs, cyclohexenes which add RMgX stereospecifically to the ketone. A final product in this sequence is the intensely sweet sesquiterpene, hernandulcin.