115693-93-1Relevant academic research and scientific papers
THE WITTIG-HORNER ROUTE TO TRI-SUBSTITUTED ALKENES: SYNTHESIS OF Z-α-BISABOLENE
Buss, Antony D.,Warren, Stuart
, p. 111 - 114 (1983)
E and Z isomers of trisubstituted alkenes may separately be prepared by the Wittig-Horner reaction.Z-α-bisabolene has been made by this route.
Applications of the Stereochemically-Controlled Horner-Wittig Reaction: Synthesis of Feniculin, (E)-Non-6-en-1-ol, a Pheromone of the Mediterranean Fruit Fly, (E)- and (Z)-Dec-5-en-1-ol, Tri-substituted Alkenes, and (Z)-α-Bisabolene
Buss, Antony D.,Greeves, Nicholas,Mason, Ralph,Warren, Stuart
, p. 2569 - 2578 (2007/10/02)
Stereoselective reduction of the appropriate α-diphenylphosphinoyl ketone or addition of the lithium derivative of an alkyl diphenylphospine oxide to an aldehyde or a ketone gives Horner-Wittig intermediates and hence the title compounds.
