115694-82-1Relevant articles and documents
Enzymatic procedure for the synthesis of prostaglandin A2
Suemune,Tanaka,Obaishi,Sakai
, p. 15 - 21 (1988)
-
Stereoselective total synthesis of (-)-borrelidin
Vong, Binh G.,Kim, Sun Hee,Abraham, Sunny,Theodorakis, Emmanuel A.
, p. 3947 - 3951 (2007/10/03)
A convergent synthesis of (-)-borrelidin (1) is reported based on the retrosynthetic disconnections indicated in the picture. Highlights of the strategy include the construction of a strained enynone-containing macrolide and the installation of a cyano group in a regioselective manner by a novel molybdenum-catalyzed hydrostannation of the alkyne.