115757-11-4Relevant academic research and scientific papers
Carbaborane-based alkynylphosphanes and phospholes
Kreienbrink, Anika,Srosi, Menyhrt B.,Kuhnert, Robert,Wonneberger, Peter,Arkhypchuk, Anna I.,L?nnecke, Peter,Ott, Sascha,Hey-Hawkins, Evamarie
, p. 836 - 838 (2015)
The reaction of 1,2-bis(N,N-dimethylaminochloro-phosphanyl)-1,2-dicarba-closo-dodecaborane(12) and lithiated phenylacetylene gives a five-membered dihydrophosphole derivative with an exocyclic phosphanyl group. This unexpected reaction opens new possibilities for the synthesis of carbaborane-containing phosphorus heterocycles. P,P′-alkynylated 1,2-bis(phosphanyl)-1,2-dicarba-closo-dodecaborane(12)s are obtained from alkynylchlorophosphanes and dilithiated carbaborane. This new class of alkynes can be used for future applications in cyclizations and polymerizations. This journal is
