115804-87-0Relevant academic research and scientific papers
Neutral and cationic carbonyl complexes of manganese with tetramethylthiourea. Crystal structure of cis-2)2>ClO4
Carriedo, C.,Sanchez, M. V.,Carriedo, G. A.,Riera, V.,Solans, X.,Valin, M. L.
, p. 53 - 62 (1987)
Tetramethylthiourea (TMTU) reacts with Mn2(CO)10 in hexane under UV irradiation to give axial Mn2(CO)9(TMTU), with MnBr(CO)5 in CH2Cl2 at room temperature to give cis-MnBr(CO)4(TMTU) and with Mn(OClO3)(CO)5 in CH2Cl2 to give the cationic tetracarbonyl cis
