1158080-74-0Relevant articles and documents
Convenient synthesis of optically active deuterated primary alcohols via deuteride reduction of acetals derived from homochiral (1R*,2R*)-3,3,3-trifluoro-1-phenylpropane-1,2-diols
Morelli, Carlo F.,Cairoli, Paola,Marigolo, Tiziana,Speranza, Giovanna,Manitto, Paolo
, p. 351 - 354 (2009)
(1R)-1-Deuterated alcohols with high enantiomeric excess were prepared via TiCl4/Et3SiD reduction of acetals arising from the reaction of aldehydes with (1S,2S)-3,3,3-trifluoro-1-phenylpropane-1,2-diol 9. Such a chiral auxiliary was