115809-06-8Relevant academic research and scientific papers
UNEXPECTED ROUTE TO SUBSTITUTED 4,6-DINITROANTHRANILS BY OXIDATION OF ANIONIC ?-COMPLEXES OF 1,3,5-TRINITROBENZENE
Kovalenko, S. V.,Artamkina, G. A.,Terent'ev, P. B.,Shevtsov, V. K.,Beletskaya, I. P.,Reutov, O. A.
, p. 357 - 361 (2007/10/02)
Oxidation of anionic ?-complexes of trinitrobenzene with C-C bonds by the CuBr/CCl4 system forms 3-R-4,6-dinitroanthranils.When this reaction is carried out a CH2R group must be at the geminal node of the ?-complex and 18-crown-6-ether.
