1158177-81-1

Basic information

• Product Name: [Rh(cyclooctadiene)((S)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-dinaphthalen-4-yl)dimethylamine)(P(C₆H₅)2C₇H₇N₂O)]BF₄
• CAS NO: 1158177-81-1
• Molecular Weight: 977.588
• Mol File: 1158177-81-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Rh(cyclooctadiene)((S)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-dinaphthalen-4-yl)dimethylamine)(P(C₆H₅)2C₇H₇N₂O)]BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: [Rh(cyclooctadiene)((S)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-dinaphthalen-4-yl)dimethylamine)(P(C₆H₅)2C₇H₇N₂O)]BF₄(1158177-81-1)
• EPA Substance Registry System: [Rh(cyclooctadiene)((S)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-dinaphthalen-4-yl)dimethylamine)(P(C₆H₅)2C₇H₇N₂O)]BF₄(1158177-81-1)

Safety Data

• Hazardous Substances Data: 1158177-81-1(Hazardous Substances Data)

Upstream product

• 35138-22-8 bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 
• 157488-65-8 (S)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']-dinaphthalen-4-yl)dimethylamine 
• 1158177-62-8 1-(3-(diphenylphosphanyl)phenyl)urea 

Relevant articles and documents

Singly hydrogen bonded supramolecular ligands for highly selective rhodium-catalyzed hydrogenation reactions

(Chemical Presented) H bonds make the catalyst! A single hydrogen bond between ligands coordinated to a rhodium center is critical for the formation of pure supramolecular catalyst for asymmmetric hydrogenation reactions. The ester group of the amidite ligand (see scheme) also forms a hydrogen bond with the coordinated substrate. Use of the herecomplex afforded the highest enantioselectivity reported to date for the hydrogenation of several ester substrates.