115822-08-7Relevant academic research and scientific papers
15N Nuclear Polarisation in Nitration and Related Reactions. Part 8. The Mechanisms of Rearrangement of 2-Methyl-2-nitrocyclohexa-3,5-dienones
Ridd, John H.,Trevellic, Susan,Sandall, John P. B.
, p. 1073 - 1079 (2007/10/02)
A kinetic study has been carried out on the regiospecific rearrangement of 2-methyl-2-nitrocyclohexa-3,5-dienone to 2-methyl-6-nitrophenol in acetic anhydride containing 0.2percent sulfuric acid at -27.8 to -6.5 deg C.Related studies have been carried out
FORMATION OF DIENONES ON THE REACTION OF CRESOLS, XYLENOLS, AND 2-NAPHTHOL WITH NITROGEN DIOXIDE: OBSERVATION OF KETO TAUTOMERS OF NITROPHENOLS
Fischer, Alfred,Mathivanan, N.
, p. 1869 - 1872 (2007/10/02)
Reaction of o- and p-cresol, the xylenols, and 2-naphthol with nitrogen dioxide gives nitrocyclohexadienones and nitrophenols.Secondary nitrodienones, the keto tautomers of the nitrophenols, have been observed in several cases and are intermediates in the formation of the nitrophenols.
