1158386-08-3Relevant academic research and scientific papers
New synthetic strategies for the stereocontrolled synthesis of substituted 'skipped' diepoxides
Morten, Christopher J.,Jamison, Timothy F.
scheme or table, p. 6648 - 6655 (2011/02/26)
This report describes a number of new synthetic approaches toward methyl-substituted mono- and diepoxy alcohols that serve as substrates for endo-selective epoxide-opening cascades. The key transformations involve the manipulation of alkynes. Highlighted
Water overcomes methyl group directing effects in epoxide-opening cascades
Morten, Christopher J.,Jamison, Timothy F.
supporting information; experimental part, p. 6678 - 6679 (2009/10/30)
(Chemical Equation Presented) Water is an effective promoter of the endo-selective opening of trisubstituted epoxides, enabling related cascadesleading to a variety of substituted ladder polyether structures. When u sed in conjunction with a tetrahydropyr
