115889-47-9Relevant academic research and scientific papers
THE STEREOSELECTIVITY OF DIRECTED ALDOL REACTIONS WITH 3-NITRO-2-METHOXYBENZALDEHYDES IS AFFECTED BY THE AMINE EMPLOYED AS BASE.
Baker, Raymond,Castro, Jose L.,Swain, Christopher J.
, p. 2247 - 2250 (2007/10/02)
Reactions of 3-nitro-2-methoxybenzaldehydes with the boron enolate of a chiral propionyl oxazolidone has been demonstrated to yield poor diastereoselection in the presence of i-Pr2NEt as base whereas the use of Et3N results in 98percent diastereoselection
