Cas 1158910-54-3,(S)-methyl 6-(tert-butyldiphenylsilyloxy)-4-hydroxyhex-2-ynoate

1158910-54-3

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Basic information

Product Name: (S)-methyl 6-(tert-butyldiphenylsilyloxy)-4-hydroxyhex-2-ynoate
Synonyms: (S)-methyl 6-(tert-butyldiphenylsilyloxy)-4-hydroxyhex-2-ynoate
CAS NO:1158910-54-3
Molecular Formula:
Molecular Weight: 396.558
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (S)-methyl 6-(tert-butyldiphenylsilyloxy)-4-hydroxyhex-2-ynoate(CAS DataBase Reference)
NIST Chemistry Reference: (S)-methyl 6-(tert-butyldiphenylsilyloxy)-4-hydroxyhex-2-ynoate(1158910-54-3)
EPA Substance Registry System: (S)-methyl 6-(tert-butyldiphenylsilyloxy)-4-hydroxyhex-2-ynoate(1158910-54-3)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 1158910-54-3(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 1158910-54-3 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,5,8,9,1 and 0 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1158910-54:
(9*1)+(8*1)+(7*5)+(6*8)+(5*9)+(4*1)+(3*0)+(2*5)+(1*4)=163
163 % 10 = 3
So 1158910-54-3 is a valid CAS Registry Number.

1158910-54-3Upstream product

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1158910-54-3Relevant academic research and scientific papers

Highly enantioselective catalytic alkyl propiolate addition to aliphatic aldehydes

Turlington, Mark,DeBerardinis, Albert M.,Pu, Lin

, p. 2441 - 2444 (2009)

A novel H8BINOL-based chiral ligand (S)-3 is found to catalyze the alkyl propiolate addition to aliphatic aldehydes in the presence of ZnEt2 and Ti(OiPr)4 at room temperature with excellent enantioselectivity (89-97% ee).

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