1159205-60-3Relevant academic research and scientific papers
Pd-catalyzed dearboxylative heck coupling with dioxygen as the terminal oxidant
Fu, Zhengjiang,Huang, Shijun,Su, Weiping,Hong, Maochun
supporting information; experimental part, p. 4992 - 4995 (2010/12/25)
Pd-catalyzed decarboxylative Heck coupling of aromatic carboxylic acids with various olefins is developed using O2 as the terminal oxidant. Enhancement of O2 pressure leads to improving reaction turnover in this transformation and allows significantly reducing catalyst loading for efficient conversion of electron-rich benzoic acids. A Pd catalyst supported by a carbene ligand enables using electron-deficient benzoic acids as coupling partners.
Pd(O2CCF3)2/benzoquinone: A versatile catalyst system for the decarboxylative olefination of arene carboxylic acids
Hu, Peng,Kan, Jian,Su, Weiping,Hong, Maochun
supporting information; experimental part, p. 2341 - 2344 (2009/09/30)
A versatile palladium catalyst system was developed to effect the decarboxylative Heck coupling of a variety of arenecarboxylic acids with a wide range of olefins. The key to obtaining the efficient catalyst system is the use of 1-adamatanecarboxylic acid
