1159252-76-2Relevant academic research and scientific papers
Radical reactions with double memory of chirality (2MOC) for the enantiospecific synthesis of adjacent stereogenic quaternary centersin solution: Cleavage and bonding faster than radical rotation
Resendiz, Marino J. E.,Family, Farnosh,Fuller, Kerrian,Campos, Luis M.,Khan, Saeed I.,et al.
supporting information; experimental part, p. 8425 - 8433 (2009/10/23)
The solution photochemistry of bis(phenylpyrrolidinonyl)ketones (R,R)-1band (S,S)-1b exhibited a remarkably high memory of chirality. Stereospe cific decarbonylation to products (R,R)-3b and (S,S)-3b, respectively, occurred with an ee of ca. 80percent. Th
