115933-40-9Relevant academic research and scientific papers
Room-temperature arylation of arenes and heteroarenes with diaryliodonium salts by photoredox catalysis
Liu, Yu-Xia,Xue, Dong,Wang, Jia-Di,Zhao, Cong-Jun,Zou, Qing-Zhu,Wang, Chao,Xiao, Jianliang
supporting information, p. 507 - 513 (2013/04/10)
Aryl radicals produced by irradiation of diaryliodonium salts with visible light under the catalysis of [Ru(bpy)3]2+ undergo coupling with a wide range of arenes and heteroarenes, affording various biaryls through direct C-H arylation at room temperature. Georg Thieme Verlag Stuttgart · New York.
Visible light-mediated direct arylation of arenes and heteroarenes using diaryliodonium salts in the presence and absence of a photocatalyst
Tobisu, Mamoru,Furukawa, Takayuki,Chatani, Naoto
supporting information, p. 1203 - 1205 (2013/10/22)
Diaryliodonium salts have been used as aryl radical sources under visible light-mediated photoredox catalysis. Benzene and a range of heteroarenes are arylated with Ar2I+ in the presence of [Ir(ppy)2(bpy)] PF6 upon irradiation with visible light. When pyrroles are used, the arylation proceeds in the absence of a photoredox catalyst. Both processes are initiated by photoinduced single-electron-transfer to Ar2I+, generating aryl radicals.
Palladium-Catalysed Direct Polyarylation of Pyrrole Derivatives
Zhao, Liqin,Bruneau, Christian,Doucet, Henri
, p. 255 - 262 (2013/03/28)
The palladium-catalysed direct polyarylation of 1-methylpyrrole and 1-phenylpyrrole was studied. As the C2 and C5 positions of pyrroles are more reactive for C-H bond functionalisation than the C3 and C4 positions, the formation of 2,5-diarylpyrroles was
