115936-45-3

Upstream product

• 99438-69-4 (E)-7-O-benzyl-2,3-dideoxy-4,5-O-isopropylidene-D-ribo-hept-2-enitol 
• 198969-39-0 5-O-benzyl-2,3-O-isopropylidene-D-ribofuranose 
• 99409-40-2 (Z)-ethyl-7-O-benzyl-4,5-O-isopropylidene-2,3-dideoxy-D-ribohept-2-enonate 
• 99409-42-4 ethyl(E)-7-O-benzyl-2,3-dideoxy-4,5-O-isopropylidene-D-ribo-hept-2-enoate 
• 115828-21-2 (Z)-3-{(4S,5S)-5-[(R)-2-Benzyloxy-1-(tetrahydro-pyran-2-yloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-acrylic acid ethyl ester 
• 115828-22-3 (E)-3-{(4S,5S)-5-[(R)-2-Benzyloxy-1-(tetrahydro-pyran-2-yloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-acrylic acid ethyl ester 

Relevant academic research and scientific papers

Stereoselectivity in Electrophile-Mediated Intramolecular Cyclizations of Hept-2-enitols

Electrophile (dibromine, diiodine, benzeneselenenyl chloride, and mercuric acetate) mediated intramolecular cyclization of (Z)-7-O-benzyl-1,2,3-trideoxy-4,5-O-isopropylidene-D-ribo-hept-2-enitol (9) gives predominantly 2,5-anhydro-1-O-benzyl-6,7-dideoxy-6

ELECTROPHILE-MEDIATED CYCLIZATIONS IN CARBOHYDRATE CHEMISTRY: SYNTHESYS OF HIGHLY FUNCTIONALIZED RIBOFURANOSE AND RIBOPYRANOSE COMPOUNDS

Iodine-mediated cyclization of (Z)- and (E)-D-ribohept-2-enonates 1 and 2 gave exclusively the β-ribofuranose and α-ribofuranose derivatives 3 and 4, respectively.Cyclization of the (Z)- and (E)-2-heptene-1-ol derivatives 5 and 6 gave ribofuranose product