1159404-38-2

Upstream product

• 110-86-1 pyridine 
• 57501-54-9 dithiophenylglyoxime 
• 1313442-69-1 CoCl(pyridine)(dithiophenylglyoxime(-1H))(dimethylglyoxime(-1H)) 

Downstream Products

• 1159404-39-3 MeCo((bis(thiophenyl)glyoxime-H)2(pyridine) 
• 1159404-40-6 EtCo((bis(thiophenyl)glyoxime-H)2(pyridine) 
• 1159404-41-7 PrCo((bis(thiophenyl)glyoxime-H)2(pyridine) 
• 1159404-42-8 BuCo((bis(thiophenyl)glyoxime-H)2(pyridine) 
• 1159404-43-9 (benzyl)Co((bis(thiophenyl)glyoxime-H)2(pyridine) 
• 1159404-43-9 [Co(CH₂C₆H₅)((C₆H₅S(C)NO)2H)2(C₅H₅N)] 

Relevant academic research and scientific papers

Cobaloximes with mixed dioximes having C and S side chains: Synthesis, structure and reactivity

Ten mixed dioxime complexes RCo(L)(dmgH)Py [R = Cl, Me, Et, Bu, Benzyl] [L = dSPhgH (1-5) and dSEtgH (6-10)] have been synthesized and characterized by NMR. Formation of 1 and 6 is very fast and takes only 5 and 15 min in ethanol. Molecular oxygen insertion in 5 and 10 is monitored and forms mixture of products within 5 min. The crystal structure of 1, 4, 5, 6, 8 and 10 is reported. Benzyl ring is oriented over dmgH wing in both 5 and 10 and has a weak C-H...π interaction (3.33 and 3.22 ) and this causes high upfield shift of the dmgH protons. Electrochemical study on 1, 4, 5, 6, 8 and 10 is also reported. Because of increased electron donation by SEt group, 6 is more difficult to reduce than 1.

Cobaloximes with bis(thiophenyl)glyoxime: Synthesis and structure - Property relationship study

Alkyl and non-alkyl cobaloximes with bis(thiophenyl)glyoxime, X/RCo(dSPhgH)2Py (X) Cl, R) Me, Et, Pr, Bu, Bn) have been synthesized and characterized for the first time. The X-ray structures of the complexes ClCo(dSPhgH)2Py, EtCo(dSP