115993-77-6Relevant academic research and scientific papers
Generation, Some Synthetic Uses, and 1,2-Vinyl Rearrangements of Secondary and Tertiary Homoallyllithiums, Including Ring Contractions and A Ring Expansion. Remarkable Acceleration of the Rearrangement by an Oxyanionic Group
Mudryk, Boguslaw,Cohen, Theodore
, p. 3855 - 3865 (2007/10/02)
A very general preparative method for homoallyllithiums consists of reductive lithiation of homoallylithiums consists of reductive lithiation of homoallyl phenyl sulfides by lithium 4,4'-di-tert-butylbiphenylide.The sulfides can be prepared by a variety o
THE REACTION OF ALLYLSILANES WITH PHENYLTHIOACETALS IN THE PRESENCE OF ALUMINIUM TRICHLORIDE
Mann, Andre,Ricci, Alfredo,Taddei, Maurizio
, p. 6175 - 6176 (2007/10/02)
Tionium ions, generated from phenylthioacetals and AlCl3, react with several allylsilanes to give phenylthioethers which can be easily transformed into conjugated dienes.
A Convenient Method for the Transformation of Alkenyl Sulfides to 2-(Phenylthio)alkanenitriles, Homoallyl Sulfides, and Thioacetals
Takeda, Takeshi,Kaneko, Yuichiro,Nakagawa, Hitoshi,Fujiwara, Tooru
, p. 1963 - 1966 (2007/10/02)
2-(Phenylthio)alkanenitriles, homoallyl sulfides, and thioacetals were obtained in good yields by the reaction of alkenyl sulfides with the corresponding silyl nucleophiles via thionium ion intermediates.
