1159991-92-0Relevant academic research and scientific papers
Stereodefined Access to Lactams via Olefin Difunctionalization: Iridium Nitrenoids as a Motif of LUMO-Controlled Dipoles
Hong, Seung Youn,Chang, Sukbok
supporting information, p. 10399 - 10408 (2019/07/08)
Reported herein is a general platform of a stereodefined access to Γ-lactams via Cp*Ir-catalyzed olefin difunctionalization, where in situ generated Ir-nitrenoid is utilized as a key motif of 1,3-dipoles to enable amido transfer in a syn-selective manner.
Tethered aminohydroxylation (TA) reaction of amides
Donohoe, Timothy J.,Callens, Cedric K. A.,Thompson, Amber L.
supporting information; experimental part, p. 2305 - 2307 (2009/10/23)
The first examples of amide-tethered aminohydroxylation reactions, catalyzed by osmium, showing that the use of N-O-based reoxidants are essential for success, are reported. The system that is described is compatible with a variety of different alkene sub
