116005-40-4Relevant academic research and scientific papers
Access to cyclopropyl cations via carbene fragmentation
Moss, Robert A.,Chu, Gaosheng
, p. 3321 - 3326 (2007/10/03)
Photolysis of cyclopropyloxychlorodiazirines affords cyclopropyloxychlorocarbenes whose fragmentations provide access to ion pairs, which feature cyclopropyl cations.
FREE RADICAL CHLORINATION AND ONE-ELECTRON OXIDATION OF ARYLCYCLOPROPANES. DESIGNER PROBES FOR CYTOCHROME P-450 HYDROXYLATION MECHANISMS
Riley, Pamela,Hanzlik, Robert P.
, p. 3015 - 3018 (2007/10/02)
Arylcyclopropyl radicals can be formed under mild conditions (phase-transfer-catalyzed chlorination) and give rise to cyclopropyl products; in contrast one-electron oxidation of arylcyclopropanes by Mn(OAc)3 leads to fragmentation of the cyclopropane ring and the formation of acyclic products.
