116016-06-9

Basic information

• Product Name: 2-iodo-3,3,5-trimethylcyclohexanone
• Synonyms: 2-iodo-3,3,5-trimethylcyclohexanone
• CAS NO: 116016-06-9
• Molecular Weight: 266.122
• Mol File: 116016-06-9.mol

Chemical Properties

• CAS DataBase Reference: 2-iodo-3,3,5-trimethylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-iodo-3,3,5-trimethylcyclohexanone(116016-06-9)
• EPA Substance Registry System: 2-iodo-3,3,5-trimethylcyclohexanone(116016-06-9)

Safety Data

• Hazardous Substances Data: 116016-06-9(Hazardous Substances Data)

Upstream product

• 873-94-9 dihydroisophorone 

Relevant articles and documents

A New α-Iodination of Ketones Using Iodine-Ammonium Cerium(IV) Nitrate in Alcohol or Acetic Acid

The direct α-iodination of various ketones using iodine-ammonium cerium(IV) nitrate in acetic acid or alcohol gave the corresponding α-iodo ketones in high yields. The effect of cerium salt on the iodination of ketones, and the iodination of 5α-cholestan-3-one using several methods are also discussed. In the reaction of 3,3,5-trimethylcyclohexanone and unsymmetrical ketones, such as 2-hexanone and 2-heptanone, using methanol, ethanol, 1-propanol, and 2-propanol, the regioselective iodination product was obtained. In the case of bromination, the reaction of ketones with bromine and ammonium cerium(IV) nitrate also yielded the corresponding α-bromo ketones.

A New α-Iodination of Ketones Using Iodine-Cerium(IV) Ammonium Nitrate

Direct α-iodination of some ketones using iodine-cerium(IV) ammonium nitrate in acetic acid or methanol, gave the corresponding α-iodoketone in high yield.In the case of 2-pentanone, 4-methyl-2-pentanone, 2-hexanone, and 2-heptanone in methanol, the regioselective products were obtained.