1160171-97-0Relevant academic research and scientific papers
Rh(III)-catalyzed chemoselective C-H functionalizations of tertiary aniline: N -oxides with alkynes
Huang, Xiaolei,Liang, Wenbo,Shi, Yang,You, Jingsong
supporting information, p. 6253 - 6256 (2016/05/19)
In this work, we report novel Rh(iii)-catalyzed chemoselective functionalizations of tertiary aniline N-oxides with alkynes, including annulation via the sequential C(sp2)-H and C(sp3)-N activation for the formation of N-alkylindoles and an O-atom transfer (OAT) process for the synthesis of acetophenones.
Rhodium(III)-catalyzed synthesis of indoles from 1-alkylidene-2- arylhydrazines and alkynes via C-H and N-N bond cleavages
Matsuda, Takanori,Tomaru, Yuki
supporting information, p. 3302 - 3304 (2014/06/09)
1-Alkylidene-2-arylhydrazines undergo annulative coupling with internal alkynes in the presence of a rhodium(III) catalyst and a copper(II) salt. The reaction proceeds through cleavage of the C-H and N-N bonds of hydrazines to afford 1,2,3-trisubstituted indole derivatives.
Fluorescent diarylindoles by palladium-catalyzed direct and decarboxylative arylations of carboxyindoles
Miyasaka, Mitsuru,Fukushima, Azusa,Satoh, Tetsuya,Hirano, Koji,Miura, Masahiro
experimental part, p. 3674 - 3677 (2009/12/25)
A study was conducted to demonstrate the palladium-catalyzed 2,3-diarylation of carboxyindole derivatives with acryl bromides. The study also performed ester hydrolysis in the sequence to demonstrate a practical route to 2,3-diarylindoles that had differe
