116018-77-0Relevant academic research and scientific papers
Reaktive ?-Komplexe der elektronenreichen Uebergangsmetalle, IV. Cyclisierungsreaktionen von t-Butylphosphaacetylen an ?-Areneisen-Komplexen
Driess, M.,Hu, D.,Pritzkow, H.,Schaeufele, H.,Zenneck, U.,et.al.
, p. C35 - C38 (1987)
The reaction of t-butylphosphaacetylene and bis(ethene)(toluene)iron or (toluene)(1-methylnaphthalene)iron yields t-butyl derivatives of three new complexes (toluene)(1,3-diphosphete)iron (4), (1,3-diphospholyl)(1,3-diphosphete)iron (5), and (1,3-diphosph
POLYCYCLIC POLYPHOSPHORUS HYDROCARBONS
Boehm, Dieter,Hu, Dongqi,Zenneck, Ulrich
, p. 5 - 8 (2007/10/02)
Highly reactive arene iron complexes are capable of transforming tert.-butylphosphaacetylene into several coordinated organophosphorus compounds by cyclic addition reactions below or at room temperature.Free cage-structured polyphosphorus hydrocarbons are formed from the same educts by increasing the temperature or by low-temperature reduction of the phosphaalkyne.
