1160292-01-2Relevant academic research and scientific papers
Olefination of α,α′-divinyl ketones through catalytic Meyer-Schuster rearrangement
Rieder, Curtis J.,Winberg, Karl J.,West
, p. 50 - 56 (2011/03/22)
The direct olefination of 1,4-dien-3-ones remains a synthetic challenge. A two-step protocol, employing acetylide addition followed by catalytic Meyer-Schuster rearrangement has been developed for the olefination of 1,4-pentadien-3-ones to afford [3]dendr
Cyclization of cross-conjugated trienes: The vinylogous Nazarov reaction
Rieder, Curtis J.,Winberg, Karl J.,West, F. G.
supporting information; experimental part, p. 7504 - 7505 (2009/10/17)
(Chemical Equation Presented) Cross-conjugated trienoates can be readilyprepared from 1,4-pentadien-3-one precursors via a 2-step process: 1,2- addition of lithiated ethynyl ethyl ether followed by rearrangement of the resulting propargylic alcohol with c
