1160293-79-7Relevant academic research and scientific papers
Chiral tetraazamacrocycles having four pendant-arms
Kamioka, Seiji,Takahashi, Takashi,Kawauchi, Susumu,Adachi, Hiroaki,Mori, Yusuke,Fujii, Kotaro,Uekusa, Hidehiro,Doi, Takayuki
supporting information; experimental part, p. 2289 - 2292 (2009/10/02)
A chiral tetraazamacrocycle 9 having four pendant-arms was synthesized by repeating ring opening of an Ns-aziridine with secondary amines, followed by macrocyclization. The structure of 9 has been determined by single crystal X-ray diffraction analysis and NMR studies. Sugarhybrid molecules 12a-12f were synthesized based on the scaffold 9. NMR study showed that 12a-12f keep the similar conformation as 9 in solution.
