1160294-75-6

Upstream product

• 603-34-9 N,N-diphenylaminobenzene 
• 1019056-21-3 dimethyl 4-(diphenylamino)phenylboronate 
• 36809-26-4 4-N,N-diphenylamino-1-bromobenzene 
• 90-11-9 1-Bromonaphthalene 
• 201802-67-7 4-(diphenylamino)phenyl boronic acid 
• 13922-41-3 1-Naphthylboronic acid 

Downstream Products

• 1160294-76-7 (4-bromo-phenyl)-(4-naphthalen-1-yl-phenyl)-phenyl-amine 

Relevant academic research and scientific papers

Three series π-extended fluorescent compounds based on dehydroabietic acid triarylamine moiety: Syhthesis, photophysical properties and hole transporting properties

Fluorescent compounds based on a dehydroabietic acid skeleton with favorable photophysical properties show promise for use as the hole-transporting layer in organic light-emitting diodes (OLEDs). In this work, we report the synthesis of three series of compounds (15 in total), series 1 (1a–1e), series 2 (2a–2e), and series 3 (3a–3e), by linking polycyclic aromatic hydrocarbons (PAHs) to dehydroabietic acid-based triaryamine moiety through C-C coupling reactions. The three series of compounds exhibited ultraviolet absorption, fluorescence emission, electrochemical, and thermal properties, as well as highest occupied molecular orbital levels and energy gaps that made them suitable for use as hole-transporting materials. OLEDs with 1a, 2a, or 3d as a hole-transporting layer showed better performance in terms of maximum brightness, turn-on voltage, maximum of external quantum efficiency, maximum luminous efficiency and power efficiency than that of a comparable device based on a conventional hole-transporting material. In particular, the device with 1a exhibited the most promising performance, with a high maximum brightness of 21445 cd/m2, low turn-on voltage of 2.8 V, maximum of external quantum efficiency of 1.62%, maximum luminance efficiency of 4.9 cd/A, and maximum power efficiency 3.7lm/W. The present work highlights the potential of π-extended compounds based on dehydroabietic acid for use in luminescent material applications.

Crystalline triphenylamine substituted arenes: solid state packing and luminescence properties

The crystal packing and solid state photophysical properties of twisted propeller-shaped triphenylamine (T) incorporated aromatic hydrocarbons [ArT where Ar = benzene (Ph), naphthalene (N), anthracene (A), phenanthrene (Phe), pyrene (Py) and perylene (Pe)] are investigated. The qualitative crystal structure and quantum theory of atoms-in-molecules (QTAIM) analyses revealed the dominant role of intermolecular C-H...C interactions in governing the three-dimensional arrangement in ArT crystals. Hirshfeld surface analyses revealed that the triphenylamine-substituted arene (ArT) crystals possess a herringbone motif with ρ (%C-H...C/%C...C) values varying from 10.4 in PeT to 101.2 in AT. A blue shift of ca. 10-28 nm in the emission maxima for PhT, NT, AT, PheT and PyT is observed in the solid state in comparison to that in dichloromethane while the solid state emission maxima is red shifted (ca. 25-71 nm) compared to that in hexane. A 2.40-fold enhancement in the quantum yield of AT is observed in the solid state relative to the solution state (dichloromethane). Solvent polarity dependent absorption and emission measurements of ArT derivatives along with Lippert-Mataga analyses evidenced the presence of charge transfer interactions between Ar and T units. A precise and systematic understanding of the influence of the crystal structure on the photophysical properties is quintessential to achieve highly efficient organic light emitting diodes and other optoelectronic devices in the near future.

Violet-blue-or pure-blue-emitting triphenylamine derivatives: Synthesis and properties

We report the synthesis and optoelectronic properties of a series of nine triphenylamine derivatives. They were synthesized by Suzuki cross-coupling reactions and characterized by elemental analysis, nuclear magnetic resonance, ultraviolet visible absorpt

CARBAZOLE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING CARBAZOLE DERIVATIVE

To provide a light-emitting element having high luminous efficiency and to provide a light-emitting device and an electronic device which consumes low power and is driven at low voltage, a carbazole derivative represented by the general formula (1) is provided. In the formula, α1, α2, α3, and α4 each represent an arylene group having less than or equal to 13 carbon atoms; Ar1 and Ar2 each represent an aryl group having less than or equal to 13 carbon atoms; R1 represents any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; and R2represents any of an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group. In addition, l, m, and n are each independenly 0 or 1.

TRIARYLAMINE DERIVATIVE, LIGHT-EMITTING SUBSTANCE, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE

A triarylamine derivative represented by a general formula (G1) given below is provided. Note that in the formula, Ar represents either a substituted or unsubstituted phenyl group or a substituted or unsubstituted biphenyl group; α represents a substituted or unsubstituted naphthyl group; β represents either hydrogen or a substituted or unsubstituted naphthyl group; n and m each independently represent 1 or 2; and R1 to R8 each independently represent any of hydrogen, an alkyl group having 1 to 6 carbon atoms, or a phenyl group.