1160580-95-9Relevant academic research and scientific papers
Room-temperature rhodium-catalyzed asymmetric 1,4-addition of potassium trifluoro(organo)borates
Gendrineau, Thomas,Genet, Jean-Pierre,Darses, Sylvain
supporting information; experimental part, p. 3486 - 3489 (2009/12/24)
For the first time the room-temperature rhodium-catalyzed asymmetric 1,4-addition of potassium aryltrifluoroborates to αβ-unsaturated substrates is described. Thanks to the use of a chiral diene as ligand for rhodium and triethylamine as base, to facilita
Monodentate non-C2-symmetric chiral N-heterocyclic carbene complexes for enantioselective synthesis. Cu-catalyzed conjugate additions of aryl- and alkenylsilylfluorides to cyclic enones
Lee, Kang-Sang,Hoveyda, Amir H.
body text, p. 4455 - 4462 (2009/09/30)
(Chemical Equation Presented) A new class of enantioselective conjugate addition (ECA) reactions that involve aryl- or alkenylsilyl fluoride reagents and are catalyzed by chiral non-C2-symmetric Cu-based N-heterocyclic carbene (NHC) complexes a
