1160604-94-3Relevant academic research and scientific papers
Synthesis of azaaromatic?£?borane intramolecular complexes by palladium-catalyzed reaction of azaaromatic halides with alkynyl(triaryl)borates
Ishida, Naoki,Narumi, Mizuna,Murakami, Masahiro
, p. 2474 - 2480 (2013/03/29)
A diversity-oriented method to synthesize (E)-azastilbenes having an intramolecular B?£?N coordination bond from alkynyl(triaryl)borates and azaaromatic halides is described. The obtained π-conjugated compounds exhibit an intense blue fluorescence and a high electron affinity, indicating their potential to be used as n-type light-emitting materials. Copyright
NOVEL BORON COMPOUND, METHOD FOR PRODUCING THE SAME, AND FUNCTIONAL ELECTRONIC DEVICE USING THE SAME
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Page/Page column 212-213, (2010/10/05)
The present invention provides novel boron compounds which are useful, depending on their characteristics, as light-emitting materials, electron-transport materials, electron-injection materials, hole-blocking materials, or organic semiconductor materials, and which have new molecular structures quite different from those of the heretofore known boron compounds; their production processes; and functional electronic devices using the same. The novel boron compounds are, for example, those of the following formula (1): These boron compounds can be produced by, for example, reacting boron compounds of the following formula (4): with compounds of the following formula (5): in the presence of a catalyst containing at least one metal element selected from the group consisting of palladium, platinum, and nickel. These boron compounds are used for the functional electronic devices.
