1160826-91-4Relevant articles and documents
Controlled [3+2] and [2+2] Cycloadditions of 1,3-Bifunctional Allenes with C60 by Using a Flow Reaction System
Ueda, Mitsuhiro,Hayama, Miho,Hashishita, Hiroyuki,Munechika, Aiko,Fukuyama, Takahide
, p. 6764 - 6769 (2019)
The reaction of 1,2-diaryl-1,2-diketones, propiolic acid esters, and C60 in the presence of Et3N gave cyclopentene-annulated fullerenes through a [3+2] cycloaddition. They were formed in two Et3N-promoted steps, namely, th
Ambiphilic allenes: Synthesis and reactivity
Tejedor, David,Mendez-Abt, Gabriela,Gonzalez-Platas, Javier,Ramirez, Miguel A.,Garcia-Tellado, Fernando
supporting information; experimental part, p. 2368 - 2370 (2009/09/06)
Ambiphilic allenes are generated by an organocatalyzed domino reaction of alkyl propiolates and aromatic 1,2-diketones; in the absence of any external chemical agent, these allenes perform a thermally-driven dimerization reaction to generate the correspon