1160855-16-2Relevant academic research and scientific papers
Ligand-controlled cross-dimerization and -trimerization of alkynes under nickel catalysis
Matsuyama, Naoto,Tsurugi, Hayato,Satoh, Tetsuya,Miura, Masahiro
scheme or table, p. 2274 - 2278 (2009/10/14)
The cross-dimerization of diphenylacetylene with trimethylsilylacetylene via C-H bond cleavage in the presence of a catalytic amount of bis(cyclooctadiene)nickel [Ni(cod)2] together with a pyridine-based ligand efficiently proceeds to give the corresponding enyne compound with good yield. In contrast, their 1:2 cross-trimerization leading to a dienyne derivative takes place selectively using a triarylphosphine ligand. The regioselective cross-dimerization of some unsymmetrical internal arylalkynes with terminal silylacetylenes is also accomplished using the pyridine ligand.
