116102-44-4Relevant academic research and scientific papers
Application of the Sonogashira coupling reaction to the stereoselective synthesis of chiral 1,3-dienol ethers
Dussault, Patrick H.,Sloss, Darby G.,Symonsbergen, David J.
, p. 1387 - 1389 (2007/10/03)
Sonogashira couplings of 2-iodo enol ethers or ynol ethers provide enynes which undergo semihydrogenation to afford 4-alkyl-1,3-dienol ethers. (1Z, 3E), (1E, 3Z) and (1Z, 3Z)-4-alkyl-1,3-dienol ethers are accessible using this strategy.
A convenient synthesis of hexacarbonyldicobalt complexes of chiral (non-racemic) terminal alkoxyacetylenes
Bernardes, Vania,Verdaguer, Xavier,Moyano, Albert,Pericas, Miquel A.,Riera, Antoni,Greene, Andrew E.
, p. C12 - C14 (2007/10/02)
The hexacarbonyldicobalt complexes of chiral (non-racemic) unsubstituted terminal alkoxyacetylenes have been synthesized for the first time by a novel procedure that involves one-pot transformation of a chiral alcohol to the corresponding trimethylsilylat
The Resolution of Racemic Hydroperoxides: The Preparation of Optically Pure Hydroperoxide Natural Products
Dussault, Patrick,Porter, Ned A.
, p. 6276 - 6277 (2007/10/02)
We report the resolution of unsaturated hydroperoxide enantiomers by liquid chromatography of diastereomeric derivatives.This method allows the nonenzymatic preparation of optically pure allylic or dienylic hydroperoxide natural products.
