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Relevant academic research and scientific papers

Both end-on and end-to-end azide bridged tetranuclear ferromagnetic nickel(II) Schiff base complexes

Variable temperature magnetic measurements of a novel tetranuclear nickel(ii) complex, consisting of two pseudo-dinuclear entities bridged by an end-to-end azide, indicate the presence of both intra- and inter-dinuclear ferromagnetic interactions (J1 = 16.48 cm-1 and J2 = 24.17 cm-1, respectively), as also corroborated by DFT calculations (J1 = 12.0 cm-1 and J2 = 29.2 cm-1).

A combined experimental and theoretical study on two new dinuclear cadmium(II) Schiff base complexes with selenocyanate-κ-Se

Two new dinuclear cadmium(II) complexes, [Cd(L1)2Cd(SeCN-κ-Se)2] (1) and [Cd(L2)2Cd(SeCN-κ-Se)2] (2), where HL1?=?{2-(3-(dimethylamino)propyliminomethyl)-6-methoxyphenol} and HL

Synthesis and crystal structures of two dinuclear Schiff base cadmium(II) complexes

Two new dinuclear Schiff base cadmium(II) complexes with the formulae [Cd2(DM)2(NCS)2] (1) and [Cd 2(MP)2(NO3)2] (2) (DM is 2-[(3-dimethylaminopropylimino)methyl]-6-methoxyphenol

Synthesis, Crystal Structures, and Anti-cervical Cancer Activity Evaluation of Three Trinuclear Transition Metal(II) Complexes with N,O-Donor Schiff Base Ligand

A new bi-nucleating Schiff base ligand, 2-(((3-(dimethylamino)propyl)imino)methyl)-6-methoxyphenol (HL1) was prepared by a one-pot condensation reaction, which was further used in the construction of three trinuclear Schiff base transition metal(II) complexes [Cu3(L1)2(OH)2(H2O)2](NO3)2 (1), [Co3(L1)2(OH)2(H2O)2](NO3)2 (2), and [Cu3(L1)2(N3)4] (3). Furthermore, a green hand grinding technique was implemented to reduce the particle size of the coordination complexes to generate the nanoscale compounds. The SEM studies reveal the formation of square and spherical particles for nano 1 and 2, and nanorod for nano 3. In addition, the anti-proliferation activity of nano 1–3 was detected on the human cervical cancer Hela cells with CCK-8 assay. The cell viability curves and IC50 values indicated that only nano 1 has anti-proliferation activity on Hela cells. To further investigate the mechanism of nano 1 induced Hela cell death, the Annexin V-FITC/PI double staining assay, western blot assay, and ROS level detection was conducted.

Variation in molecular and crystalline architectures of di- and poly-nuclear cadmium(II) complexes on changing the denticity of the blocking ligands

Three cadmium(II) complexes, [Cd(dmpn)(μ-1,1-N3) 2]n (1), [Cd(L1)2Cd(N 3)2] (2) and [Cd2(L2) 2(Cl)2] (3) {where dmpn is a bidentate ch

The ability of a trinuclear zinc(II) Schiff base complex to act as a photocatalyst for the degradation of methylene blue and to mimic phosphatase

A new trinuclear zinc(II) complex, [Zn(μ1,1-N3)2{Zn(L)(N3)}2]·0.5CH3OH {HL = [2-((3-(dimethylamino)propylimino)methyl)-6-methoxyphenol]} has been synthesized and characterized. X-ray crysta

Formation of three photoluminescent zinc(II) complexes with Zn2O2 cores: Examples of bi-dentate bonding modes of potentially tri- and tetra-dentate Schiff bases

The 1:1 condensation of N,N-dimethyl-1,3-diaminoethane with 5-bromosalicylaldehyde, 3-methoxysalicylaldehyde and 3-ethoxysalicyalaldede produces three Schiff bases, HL1 [2-(-(3-(dimethylamino)propylimino)methyl)-4-bromophenol], HL2 [

Formation of three photoluminescent dinuclear cadmium(II) complexes with Cd2O2 cores

Condensation of N,N-dimethyl-1,3-diaminpropane with salicylaldehyde, 3-methoxysalicylaldehyde and 3-ethoxysalicylaldehyde produces three Schiff bases, HL1 [2-(3-(dimethylamino)propylimino)methyl)methoxyphenol], HL2 [2-(3-(dimethylami