1161079-18-0Relevant articles and documents
Copper(I)-catalyzed one-pot synthesis of 2-iminobenzo-1,3-oxathioles from ortho-iodophenols and isothiocyanates
Lv, Xin,Liu, Yunyun,Qian, Weixing,Bao, Weiliang
, p. 2507 - 2512 (2008)
A novel and efficient formation of 2-iminobenzo-1,3-oxathioles from readily available precursors via a copper(I)-catalyzed one-pot cascade process has been developed. Various 2-iminobenzo-1,3-oxathioles, which might be useful in pharmaceutical and biochemical areas, were conveniently synthesized in good to excellent yields.
Copper/N,N,N',N'-tetramethylethylenediamine-catalyzed synthesis of N-substituted benzoheterocycles via C-S cross-coupling at ambient temperature in water
Zhao, Na,Liu, Liang,Wang, Fei,Li, Jia,Zhang, Wu
supporting information, p. 2575 - 2579 (2014/09/17)
Copper/N,N,N',N'-tetramethylethylenediamine (Cu/TMEDA)-catalyzed ambient temperature tandem reactions of isothiocyanates with 2-iodophenols or 2-iodoanilines in water without the protection of an inert atmosphere are described, which provide a simple, rapid, environmental method for the synthesis of a variety of 2-iminobenzo-1, 3- oxathioles and 2-aminobenzothiazoles in good yields. More important, the present reaction process needs only low amounts of copper catalyst (1mol%) and can yield the products on a gram scale.
Copper(I)-catalyzed tandem reaction of 2-iodophenols with isothiocyanates in room temperature ionic liquids
Yao, Fang,Hao, Wenyan,Cai, Ming-Zhong
, p. 137 - 142 (2013/02/22)
A copper(I)-catalyzed tandem reaction of 2-iodophenols with isothiocyanates in hydrophobic [bmim][PF6] ionic liquid was described, which proceeded smoothly and generated a variety of 2-iminobenzo-1,3-oxathioles in good to excellent yields. The
