116113-76-9

Upstream product

• 129706-93-0 methyl 3-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 106711-52-8 Acetic acid (2R,3R,4S,5R,6R)-5-acetoxy-4-benzyloxy-2-bromo-6-methyl-tetrahydro-pyran-3-yl ester 
• 106711-52-8 Acetic acid (2R,3R,4S,5R,6R)-5-acetoxy-4-benzyloxy-2-bromo-6-methyl-tetrahydro-pyran-3-yl ester 

Downstream Products

• 131589-96-3 methyl 3-O-benzyl-2-O-(3-O-benzyl-6-deoxy-β-D-glucopyranosyl)-β-D-glucopyranoside 
• 116113-78-1 methyl 4,6-bis-O-(chloroacetyl)-3-O-benzyl-2-O-(2,4-bis-O-(chloroacetyl)-3-O-benzyl-6-deoxy-β-D-glucopyranosyl)-β-D-glucopyranoside 
• 116113-77-0 methyl 3-O-benzyl-2-O-(2,4-di-O-acetyl-3-O-benzyl-6-deoxy-β-D-glucopyranosyl)-β-D-glucopyranoside 

Relevant academic research and scientific papers

Phyllanthoside-Phyllanthostatin Synthetic Studies. 9. Total Syntheses of (-)-Phyllanthostatin 1, (+)-Phyllanthostatin 2, and (+)-Phyllanthostatin 3

Phyllanthostatins 1, 2, and 3 (2-4) have been synthesized for the first time. The unusual 1′→2β glycosidic linkages of the disaccharide moieties were constructed via anchimerically-assisted Koenigs-Knorr reactions. The novel β-glycosyl esters were then ge

THE TOTAL SYNTHESIS OF (+)-PHYLLANTHOSTATIN 2

The first total synthesis of the antitumor glycoside phyllanthostatin 2 (3) is reported utilizing a Mitsunobu glycosidation protocol to unite the disaccharide and aglycone moieties.