116127-28-7

Basic information

• Product Name: (6E,10E,14E,18E,22E,26E)-17-Benzenesulfonyl-2,6,10,14,19,23,27,31-octamethyl-dotriaconta-2,6,10,14,18,22,26,30-octaen-16-ol
• CAS NO: 116127-28-7
• Molecular Weight: 703.126
• Mol File: 116127-28-7.mol

Chemical Properties

• CAS DataBase Reference: (6E,10E,14E,18E,22E,26E)-17-Benzenesulfonyl-2,6,10,14,19,23,27,31-octamethyl-dotriaconta-2,6,10,14,18,22,26,30-octaen-16-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (6E,10E,14E,18E,22E,26E)-17-Benzenesulfonyl-2,6,10,14,19,23,27,31-octamethyl-dotriaconta-2,6,10,14,18,22,26,30-octaen-16-ol(116127-28-7)
• EPA Substance Registry System: (6E,10E,14E,18E,22E,26E)-17-Benzenesulfonyl-2,6,10,14,19,23,27,31-octamethyl-dotriaconta-2,6,10,14,18,22,26,30-octaen-16-ol(116127-28-7)

Safety Data

• Hazardous Substances Data: 116127-28-7(Hazardous Substances Data)

Upstream product

• 38818-91-6 (((2E,6E,10E)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraen-1-yl)sulfonyl)benzene 

Downstream Products

• 540-04-5 phytoene 
• 116059-44-0 ((6E,10E,14E,16Z,18E,22E,26E)-2,6,10,14,19,23,27,31-Octamethyl-dotriaconta-2,6,10,14,16,18,22,26,30-nonaene-16-sulfonyl)-benzene 
• 116059-40-6 Acetic acid (3E,7E,11E)-2-benzenesulfonyl-4,8,12,16-tetramethyl-1-((1E,5E,9E)-2,6,10,14-tetramethyl-pentadeca-1,5,9,13-tetraenyl)-heptadeca-3,7,11,15-tetraenyl ester 

Relevant articles and documents

Syntheses with Sulfones L : Preparation of β-Hydroxysulfones through the Combined Oxidative Desulfonylation/Condensation Reaction of Sulfonyl Anions. Application to Terpene Synthesis.

The oxidative desulfonylation of primary sulfonyl anions with the molybdenum peroxide reagent, MoO5.Py.HMPA, leads directly to β-hydroxysulfones through condensation of the starting α-sulfonyl anion with the aldehyde formed in situ.Symmetrical polyenes such as (Z)-12-dehydrosqualene and (Z)-16-phytoene have been obtained in three steps in > 87percent stereoslectivity from the corresponding β-hydroxysulfones.