116154-22-4Relevant academic research and scientific papers
Sulfonic acid functionalized ionic liquids for dissolution of metal oxides and solvent extraction of metal ions
Dupont, David,Raiguel, Stijn,Binnemans, Koen
, p. 9006 - 9009 (2015)
New sulfonic acid functionalized ionic liquids (SAFILs) with bis(trifluoromethylsulfonyl)imide anions were synthesized. These ionic liquids are strong Br?nsted acids and can solubilize metal oxides. Water-immiscible SAFILs were used as organic phases in s
Robust acidic pseudo-ionic liquid catalyst with self-separation ability for esterification and acetalization
Shi, Yingxia,Liang, Xuezheng
, p. 1413 - 1421 (2019/05/04)
The novel acidic pseudo-ionic liquid catalyst with self-separation ability has been synthesized through the quaternization of triphenylphosphine and the acidification with silicotungstic acid. The pseudo-IL showed high activities for the esterification with average conversions over 90%. The pseudo-IL showed even higher activities for acetalization than traditional sulfuric acid. The homogeneous catalytic process benefited the mass transfer efficiency. The pseudo-IL separated from the reaction mixture automatically after reactions, which was superior to other IL catalysts. The high catalytic activities, easy reusability and high stability were the key properties of the novel catalyst, which hold great potential for green chemical processes.
Straightforward Hantzsch four- and three-component condensation in the presence of triphenyl(propyl-3-sulfonyl)phosphoniumtrifluoromethanesulfonate {[TPPSP]OTf} as a reusable and green mild ionic liquid catalyst
Vahdat, Seyed Mohammad,Zolfigol, Mohammad Ali,Baghery, Saeed
, p. 311 - 317 (2016/05/02)
Triphenyl(propyl-3-sulfonyl)phosphoniumtrifluoromethanesulfonate {[TPPSP]OTf} as a reusable, green and benign ionic liquid catalyst has been used in the Hantzsch four-component (synthesis of polyhydroquinolines) and three-component (synthesis of acridines
Highly efficient triphenyl(3-sulfopropyl)phosphonium functionalized phosphotungstic acid on silica as a solid acid catalyst for selective mono-allylation of acetals
Kamble, Sumit B.,Shinde, Suhas H.,Rode, Chandrashekhar V.
, p. 4039 - 4047 (2015/08/03)
Silica supported phosphotungstic acid functionalized with triphenyl(3-sulfopropyl)phosphonium (PW-Si/TPSP) was developed as a solid acid catalyst for C-C bond formation via Hosomi-Sakurai allylation of acetals. Functionalization of PW as well as its bindi
Synthesis of highly substituted imidazoles using Bronsted acidic ionic liquid, triphenyl(propyl-3-sulphonyl)phosphonium toluenesulfonate, as reusable catalyst
Shaterian,Ranjbar,Azizi
experimental part, p. 1120 - 1134 (2012/02/04)
Bronsted acidic ionic liquid, triphenyl(propyl-3-sulphonyl) phosphonium toluenesulfonate, has been used as an efficient and reusable catalyst for the one-pot synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles under solvent-free conditions in excellent yields.
