116159-65-0Relevant academic research and scientific papers
Organylthio(silyl)carbenes
Wagner, Tobias,Lange, Jens,Grote, Dirk,Sander, Wolfram,Schaumann, Ernst,Adiwidjaja, Gunadi,Adam, Arnold,Kopf, Juergen
, p. 5198 - 5207 (2009)
The title carbenes 5 can be generated either from diazo compounds 9 by copper-catalyze d catalysis or from chloro(organylthio)methylsilanes 12 by base-induced α-elimination, This is confirmed, by [2+1] cycloadditions with alkenes to give the cyclopropanes
