1161882-48-9Relevant academic research and scientific papers
Synthesis of some nickel(II) diphosphine complexes having coordinated carboxylates
Serindag, Osman,Keles, Mustafa
, p. 445 - 447 (2008)
Treatment of aminobis(methylphosphine) complexes of nickel(II) with carboxylic acids in the presence of silver(I) salts in dichloromethane gives the corresponding nickel(II) complexes of the type [NiA(P-P] where A = CO3-- (carbonate), (2),2- - OC6H4CO2- (salicylate, Sal), (3),-O2CCH2CH2 CH(NH2)CO2- (glutamate, Glu), (4), -O2 CCH2CH2CO2- (succinicate, Suc), (5); P-P = (Cy2PCH2)2NMe (dcpam), (Ph2PCH2)2NMe (dppam). The complexes have been characterized by spectroscopic techniques such as 31P-{1H} NMR, FT-IR, UV-Vis. and mass spectrometry. Copyright Taylor & Francis Group, LLC.
Synthesis of some nickel(II) diphosphine complexes having coordinated carboxylates
Serindag, Osman,Keles, Mustafa
, p. 580 - 583 (2009/06/28)
Treatment of aminobis(methylphosphine) complexes of nickel(II) with carboxylic acids in the presence of silver(I) salts in dichloromethane gives the corresponding nickel(II) complexes of the type [NiA(P-P] where A = CO 3- (carbonate), (2), 2 - OC6H4CO2- (salicylate, Sal), (3), -O2CCH2CH2CH(NH 2)CO2- (glutamate, Glu), (4), -O2CCH 2CH2CO2- (succinicate, Suc), (5); P-P = (Cy2PCH2)2NMe (dcpam), (Ph2PCH2)2NMe (dppam). The complexes have been characterized by spectroscopic techniques such as 31P-[1H] NMR, FT-IR, UV-Vis, and mass spectrometry.
